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Gravimetric Analysis

-Introduction

-Precipitating the Pb2+ ion

-How much Na2SO4 to add

-Amount of Pb2+ in the sample

-Application Question

-Evaluation Questions



Experiment 1 Online Tutorial >> Gravimetric Analysis >> Step 3: Tutor 1

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Experiment 1 - Gravimetric Analysis

Step 3: Calculating the amount of Pb2+ in the initial sample.

In step three we weigh the mass of the final solid and calculate the amount of lead in the original sample.

The unknown sample was found to weigh 0.8758 g. The lead sulfate precipitated from the sample weighed 0.5323 g. What is the % lead in the unknown? (Please give your answer to 4 significant figures)
Hint
% Pb
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The mass of lead in lead sulfate is equal to the mass of lead in the unknown sample. Similarly, the number of moles of lead in lead sulfate is equal to the number of moles of lead in the unknown sample. How many moles of lead are there in our 0.5323 g of lead sulfate? (Note: the MW of PbSO4 is 303.258 g/mol)
Hint
Moles PbSO4
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There is 1 mole of lead in each mole of lead sulfate.
 
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Hint:
How do you convert mass of lead sulfate to moles of lead sulfate?
 
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Hint:
To convert mass of lead sulfate to moles of lead sulfate, use the Molecular Weight of PbSO4, 303.258 g/mol
 
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Hint:
The result is 0.5323 g / 303.258 g/mol = 0.001755 mol
 
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How many moles of lead are there in the unknown sample?
Hint
moles Pb
 
What is the mass of lead in the unknown sample?
 
grams Pb
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In one mole of PbSO4 there is one mole of lead, how many moles of lead are there in the unknown sample?
 
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Hint:
There are 0.001755 moles of lead in the unknown sample.
 
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Hint:
How do you convert moles of lead to mass of lead?
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Hint:
To convert from moles of lead to mass of lead use the atomic weight of Pb, 207.2 g/mol.
 
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Hint:
The result is: (0.001755 mol Pb) * (207.2 g/mol Pb) = 0.3636 g Pb.
 
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What is the percentage of lead in the unknown sample?
Hint
% Pb
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Hint:
To calculate percentage of lead in the sample, divide the mass of lead by the mass of sample and multiply by 100%.
 
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Hint:
The result is: (mass of lead / mass of sample) x 100 =
(0.3636g / 0.8758g) x 100 = 41.52%.
 
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Last Updated: Sunday, November 13th, 2022 @ 07:12:28 pm